clipped from: guitar.about.com   
100 Greatest Guitar Solos
Guitar World magazine put together a reader's poll, to find out what their readers considered to be the best guitar solos of all time. The results surely reflect the magazine's demographic (no jazz guitar solos, for example), but no one can argue the following 100 selections boast some great guitar work
What follows is the list of all 100 songs selected, listed with the guitarist who played the solo, the band who released the album, and the album name.

1.
song: Stairway to Heaven
guitarist: Jimmy Page
band: Led Zeppelin
album: Led Zeppelin IV
more: Stairway To Heaven solo details

2.
song: Eruption
guitarist: Eddie Van Halen
band: Van Halen
album: Van Halen
more: Eruption solo details

3.
song: Freebird
guitarist: Collins/Rossington
band: Lynyrd Skynyrd
album: Pronounced Leh-nerd Skin-nerd
more: Freebird solo details

4.
song: Comfortably Numb
guitarist: David Gilmour
band: Pink Floyd
album: The Wall
more: Comfortably Numb solo details

5.
song: All Along the Watchtower